Bromotriphenylmethane → 1-Bromo-5,5-dimethyl-3-triphenylmethoxy-trans-1-octene

HRID 1580408

反応式

HRID 1580408 の反応式
[Br:1]/[CH:2]=[CH:3]/[CH:4]([OH:12])[CH2:5][C:6]([CH3:11])([CH3:10])[CH2:7][CH2:8][CH3:9].[C:13]1([C:19](Br)([C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1>>[Br:1]/[CH:2]=[CH:3]/[CH:4]([O:12][C:19]([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([C:26]1[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=1)[C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)[CH2:5][C:6]([CH3:11])([CH3:10])[CH2:7][CH2:8][CH3:9]

参加物

3

反応物 2

HCID 11692BromotriphenylmethaneHCID 204657501-Bromo-5,5-dimethyl-trans-1-octen-3-ol

生成物 1

HCID 204656921-Bromo-5,5-dimethyl-3-triphenylmethoxy-trans-1-octene

実験手順

Treatment of 3.53 g. (15 moles) of 1-bromo-5,5-dimethyl-trans-1-octen-3-ol (Example 1177) with 4.85 g. (15 moles) of triphenylmethyl bromide in 35 ml. of pyridine and purification on Florisil, all as described in Example 728 gives the title compound.

後処理

  1. customof pyridine and purification on Florisil

出典と根拠

ORDレコード
ord-f9c4c5d00e2b46a3b06a47bde26af720
出典データセット
uspto-grants-1976_01
特許番号
US03932479

関連ノート

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