反応式
COCCO[Ca]O[CH2:8][CH2:9][O:10]C.[C:12]1([Na])C=[CH:16][CH:15]=[CH:14][CH:13]=1.S(=O)(=O)(O)[OH:20]>>[C:9]([OH:10])(=[O:20])[C:8]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1参加物
4
実験手順
To the suspension was added 0.2 mole of di(2-methoxyethoxy)-calcium. On stirring the mixture, the phenyl-sodium reacted and went into solution. On carbonation, followed by treatment with dilute sulfuric acid, the mixture gave 14.6 grams of benzoic acid (a 60% yield, based on the amount of chlorobenzene used), illustrating that the sodium-containing, organometallic product had the same reactivity toward carbon dioxide as does phenyl-sodium.
出典と根拠
- ORDレコード
- ord-ebb12c78fbfc4cc88a1ed962f4a19865
- 出典データセット
- uspto-grants-1976_01
- 特許番号
- US03932545
関連ノート
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