Hexadiene → HCID 22717334、化合物

HRID 1583089ノート

反応式

HRID 1583089 の反応式
[CH2:1]=[CH:2][CH:3]=[CH:4][CH2:5][CH3:6].[Cl:7][SiH:8]([Cl:10])[Cl:9]>[Cl-].C([P+](CCCC)(CCCC)CCCC)CCC>[CH3:1][CH:2]1[Si:8]([Cl:9])([Cl:7])[CH:5]([CH3:6])[CH:4]=[CH:3]1.[Cl:7][Si:8]([Cl:10])([Cl:9])[CH:2]([CH:3]=[CH:4][CH:5]([Si:8]([Cl:10])([Cl:9])[Cl:7])[CH3:6])[CH3:1]

参加物

5

反応物 2

HCID 11602HexadieneHCID 24811Trichlorosilane

生成物 2

HCID 22717334HCID 22717334、化合物収率 74%HCID 73993291HCID 73993291、化合物収率 10%

試薬・触媒・溶媒 1

HCID 75311Tetrabutylphosphonium chloride触媒

反応条件

温度
180 °C

実験手順

As in Example 1, 1,3-hexadiene (1.00 g, 12.17 mmol), trichlorosilane (6.59 g, 48.65 mmol) and tetrabutylphosphonium chloride (0.36 g, 1.22 mmol) were added in a 25 mL stainless steel tube under nitrogen atmosphere. After sealing the cylinder with a cap, the reactor was maintained at 180° C. for 8 hours. The resulting mixture was distilled to yield 1.64 g (yield: 74%) of 1,1-dichloro-2,5-dimethylsilacyclo-3-pentene and 0.43 g (yield: 10%) of 2,5-bis(trichlorosilyl)-3-hexene main products.

後処理

  1. distillationThe resulting mixture was distilled

出典と根拠

ORDレコード
ord-2d35793a6a124ce39e9777bf5c570979
出典データセット
uspto-grants-2004_05
特許番号
US06740766B2

反応ノート

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