(4-chloro-2-Methylphenoxy)acetic acid → (4-chloro-2-Methylphenoxy)acetic acid

HRID 1585830ノート

反応式

HRID 1585830 の反応式
[OH-].[K+:2].[CH3:3][C:4]1[CH:9]=[C:8]([Cl:10])[CH:7]=[CH:6][C:5]=1[O:11][CH2:12][C:13]([OH:15])=[O:14]>>[CH3:3][C:4]1[CH:9]=[C:8]([Cl:10])[CH:7]=[CH:6][C:5]=1[O:11][CH2:12][C:13]([O-:15])=[O:14].[K+:2].[CH3:3][C:4]1[CH:9]=[C:8]([Cl:10])[CH:7]=[CH:6][C:5]=1[O:11][CH2:12][C:13]([OH:15])=[O:14]

参加物

4

反応物 2

HCID 7204(4-chloro-2-Methylphenoxy)acetic acidHCID 14797Potassium Hydroxide

生成物 2

HCID 7204(4-chloro-2-Methylphenoxy)acetic acidHCID 23682017Potassium (4-chloro-2-methylphenoxy)acetate

実験手順

6.6 parts (0.1 mol) of powdered potassium hydroxide (85%) are introduced into a melt of 20 parts (0.1 mol) of MCPA (93.3%) with stirring and the mixture is kept at 130° C. for 30 minutes. After solidification, 26 parts of MCPA-potassium having an MCPA content of 71.8% are obtained, which corresponds to a yield of 100%. M.p.: 203° C.

出典と根拠

ORDレコード
ord-da9afdd0d8a24be3b24a8caa4d5f8bec
出典データセット
uspto-grants-1999_08
特許番号
US05939584

反応ノート

読み込み中…