Triethyl phosphite → Diethyl (3,3-diphenylallyl)phosphonate

HRID 1586284ノート

反応式

HRID 1586284 の反応式
[C:1]1([C:7]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:8][CH2:9]Cl)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[P:17]([O:24]CC)([O:21][CH2:22][CH3:23])[O:18][CH2:19][CH3:20]>>[C:1]1([C:7]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[CH:8][CH2:9][P:17](=[O:24])([O:21][CH2:22][CH3:23])[O:18][CH2:19][CH3:20])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

参加物

3

反応物 2

HCID 31215Triethyl phosphiteHCID 128901653-Chloro-1,1-diphenylpropene2 回

生成物 1

HCID 13328742Diethyl (3,3-diphenylallyl)phosphonate収率 108.2%

実験手順

A mixture of 40.8 g (0.155 mol) of 3,3-diphenylallyl chloride (11a) and 94.48 g (0.569 mol) of triethyl phosphite was stirred with refluxing for 24 hours. The disappearance of the 3,3-diphenylallyl chloride (11a) was ascertained, before the reaction was terminated. After cooling, the reaction mixture was distilled with a Claisen flask equipped with a vigreux to obtain 55.39 g of the target compound.

後処理

  1. temperaturewith refluxing for 24 hours
  2. customwas terminated
  3. temperatureAfter cooling
  4. distillationthe reaction mixture was distilled with a Claisen flask
  5. customequipped with a vigreux

出典と根拠

ORDレコード
ord-235c303b823b471bb6af2466609918dc
出典データセット
uspto-grants-1999_08
特許番号
US05942615

反応ノート

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