Pivaloyl-L-phenylalanine → HCID 178501412、化合物

反応式

[C:1]([NH:7][C@H:8]([C:16]([OH:18])=O)[CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=[O:6])[C:2]([CH3:5])([CH3:4])[CH3:3].[CH3:19][O:20][C:21](=[O:42])[C@H:22]([CH2:36][C:37]1[N:41]=[CH:40][NH:39][CH:38]=1)[NH:23][C:24](=[O:35])[C@H:25]([CH2:28][C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1)[NH:26][CH3:27]>>[CH3:19][O:20][C:21](=[O:42])[C@H:22]([CH2:36][C:37]1[N:41]=[CH:40][NH:39][CH:38]=1)[NH:23][C:24](=[O:35])[C@H:25]([CH2:28][C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1)[N:26]([C:16](=[O:18])[C@H:8]([CH2:9][C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=1)[NH:7][C:1](=[O:6])[C:2]([CH3:3])([CH3:4])[CH3:5])[CH3:27]

参加物

反応物 2

HCID 914376Pivaloyl-L-phenylalanine

HCID 178484875HCID 178484875、化合物

生成物 1

HCID 178501412HCID 178501412、化合物

実験手順

N-Pivaloyl-L-phenylalanine and N-methyl-L-phenylalanyl-L-histidine methyl ester are treated in the same manner as described in Example 1 to give N-pivaloyl-L-phenylalanyl-N-methyl-L-phenylalanyl-L-histidine methyl ester.

出典と根拠

ORDレコード: ord-c3b7121b3f664533b44ce39b6daf7e2a
出典データセット: uspto-grants-1993_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05202312

反応ノート

読み込み中…