HCID 21706235、化合物 → HCID 21706239、化合物

反応式

[CH2:1]([C:4]1([C:12]2[CH:17]=[CH:16][CH:15]=[C:14]([O:18][CH3:19])[CH:13]=2)[O:9][CH2:8][CH2:7][N:6]([CH3:10])[C:5]1=[O:11])[CH:2]=[CH2:3]>CO>[CH3:19][O:18][C:14]1[CH:13]=[C:12]([C:4]2([CH2:1][CH2:2][CH3:3])[O:9][CH2:8][CH2:7][N:6]([CH3:10])[C:5]2=[O:11])[CH:17]=[CH:16][CH:15]=1

参加物

実験手順

2-Allyl-2-(-3-methoxy-phenyl)-4-methyl-morpholine-3-one, as described above in Step C, (0.400 g, 1.53 mmol) was dissolved in MeOH (20 mL), the solution purged with Ar, treated with 10% Pd/C (0.060 g), and hydrogenated under a H2 balloon. After 2 h the reaction mixture was filtered through a celite pad and concentrated to dryness to give the title compound.

後処理

customthe solution purged with Ar
additiontreated with 10% Pd/C (0.060 g)
filtrationAfter 2 h the reaction mixture was filtered through a celite pad
concentrationconcentrated to dryness

出典と根拠

ORDレコード: ord-d1d3b5cce53d45f086f6e6e65979d9f2
出典データセット: uspto-grants-2001_09
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06284755B1

反応ノート

読み込み中…

参加物

反応物 1

HCID 21706235HCID 21706235、化合物

生成物 1

HCID 21706239HCID 21706239、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

後処理

customthe solution purged with Ar
additiontreated with 10% Pd/C (0.060 g)
filtrationAfter 2 h the reaction mixture was filtered through a celite pad
concentrationconcentrated to dryness

出典と根拠

ORDレコード: ord-d1d3b5cce53d45f086f6e6e65979d9f2
出典データセット: uspto-grants-2001_09
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06284755B1

反応ノート

読み込み中…