化工社化工社 化学情報印刷レポート · 研究参考用
4-Methoxybenzenethiol → Ethyl octanoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 4-Methoxybenzenethiol | HCID 12765 | — |
| 反応物 | Ethyl 2-bromooctanoate | HCID 95580 | — |
| 反応物 | 2-(4-Methoxy-phenylsulfanyl)-octanoic acid ethyl ester | HCID 11438321 | — |
| 生成物 | Ethyl octanoate | HCID 7799 | — |
反応手順
2-4-Methoxy-phenylsulfanyl)-octanoic acid ethyl ester was prepared according to the general method as outlined in example 9. Starting from ethyl-2-bromooctanoate (11.8 g, 47.3 mmol) and 4-methoxythiophenol (6 g, 43 mmol). Yield: 7.24 g (57%); clear oil; MS: 311.2 (M+H)+, 2-4-Methoxy-benzenesulfonyl)-octanoic acid ethyl ester was prepared according to the general method as outlined in example 9. Starting from 2-(4-methoxy-phenylsulfanyl)-octanoic acid ethyl ester (4.0 g, 13.6 mmol). Yield 3.7 g (83%); clear oil; MS: 343.3 (M+H)+.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06288086B1 |
| 出典データセット | uspto-grants-2001_09 |
| ORD ID | ord-dcd8fdfeaa8a41c2acdbf939d5c94c6b |
| 出典メモ | uspto-grants-2001_09 |