Water → Tma ddso

HRID 1596696

反応式

HRID 1596696 の反応式
[CH:1]1[C:6]([C:7]([Cl:9])=[O:8])=[CH:5][C:4]2[C:10]([O:12][C:13](=[O:14])[C:3]=2[CH:2]=1)=[O:11].[NH2:15][C:16]1[CH:21]=[CH:20][C:19]([S:22]([C:25]2[CH:30]=[CH:29][C:28]([NH2:31])=[CH:27][CH:26]=2)(=O)=[O:23])=[CH:18][CH:17]=1.C(N(CC)CC)C.O>CN1C(=O)CCC1>[CH:1]1[C:6]([C:7]([Cl:9])=[O:8])=[CH:5][C:4]2[C:10]([O:12][C:13](=[O:14])[C:3]=2[CH:2]=1)=[O:11].[CH:21]1[C:16]([NH2:15])=[CH:17][CH:18]=[C:19]([S:22]([C:25]2[CH:30]=[CH:29][C:28]([NH2:31])=[CH:27][CH:26]=2)=[O:23])[CH:20]=1

参加物

6

反応物 4

HCID 962WaterHCID 2955DapsoneHCID 8471TriethylamineHCID 70998Trimellitic anhydride chloride

生成物 1

HCID 131722856Tma ddso

試薬・触媒・溶媒 1

HCID 13387N-methyl-2-pyrrolidone溶媒

実験手順

At room temperature, 4.211 g (20 mmol) of trimellitic acid anhydride chloride (TMA) was added to a solution of 4.966 g (20 mmol) of bis(4-aminophenyl) sulfone in 68 ml of NMP, and the resulting mixture was stirred for 2 hours. Then, 2.9 ml (21 mmol) of triethylamine was added at 5° C. and stirred at room temperature for 10 hours. By dropwise adding the reaction mixture into 1.5 liters of water, there was obtained a polyamic acid (TMA/DDSO) as a solid product in a yield of 9.06 g.

後処理

  1. stirringstirred at room temperature for 10 hours

出典と根拠

ORDレコード
ord-80ed48ec4c6840ee83473ee92c9640a8
出典データセット
uspto-grants-2001_09
特許番号
US06291619B1

関連ノート

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