Sulfur → HCID 59968960、化合物
反応式
[CH3:1][O:2][C:3](=[O:34])[CH2:4][C@H:5]([NH:12][C:13](=[O:33])[CH2:14][NH:15][C:16](=[O:32])[CH2:17][CH2:18][CH2:19][CH2:20][NH:21][C:22]([NH:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][C:26]=1[NH2:31])=S)[C:6]1[CH:7]=[N:8][CH:9]=[CH:10][CH:11]=1.[S]>C(O)C>[CH3:1][O:2][C:3](=[O:34])[CH2:4][C@H:5]([NH:12][C:13](=[O:33])[CH2:14][NH:15][C:16](=[O:32])[CH2:17][CH2:18][CH2:19][CH2:20][NH:21][C:22]1[NH:31][C:26]2[CH:27]=[CH:28][CH:29]=[CH:30][C:25]=2[N:24]=1)[C:6]1[CH:7]=[N:8][CH:9]=[CH:10][CH:11]=1参加物
4
実験手順
An ethanol mixture (20 ml) of 24-7 (89 mg, 0.18 mmol), mercuric oxide (78.8 mg, 0.36 mmol) and sulfur (1.8 mg, 0.056 mmol) was refluxed for 2 hr. After cooling, the mixture was filtered and the filtrate concentrated to a semi-solid which was purified by flash chromatography (20% MeOH/CH2Cl2) to provide 24-8 as a solid.
後処理
- temperatureAfter cooling
- filtrationthe mixture was filtered