12-Methoxydodecanoate → 12-Methoxydodecanol

HRID 1602483ノート

反応式

HRID 1602483 の反応式
[CH3:1][O:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][C:14](O)=[O:15]>CCCCCCC.C(OCC)(=O)C>[CH3:1][O:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][OH:15]

参加物

3

反応物 1

HCID 142012-Methoxydodecanoate

生成物 1

HCID 983731312-Methoxydodecanol収率 78.2%

試薬・触媒・溶媒 1

HCID 21899848Ethylacetate heptane溶媒

実験手順

The title compound was prepared by the method of Example 3 using the title product of Example 1 (3 g, 13 mmol) instead of the title product of Example 2. Chromatography by of the crude residue on silica gel using 50--50 ethyl acetate heptane gave the title compound (2.2 g) as a white powder, m.p. 32.6-36.7° C. (DSC). The structure was supported by NMR, infrared spectroscopy, elemental analysis and mass spectroscopy.

出典と根拠

ORDレコード
ord-5fd7a9d1c86644bd913deb532f0f8cc4
出典データセット
uspto-grants-1999_11
特許番号
US05981580

反応ノート

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