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Isopropanol → 3,5-Di(2,3-epoxypropoxy)-1-hydroxyxanthone
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Isopropanol | HCID 3776 | — |
| 反応物 | Epichlorohydrin | HCID 7835 | — |
| 反応物 | Potassium Hydroxide | HCID 14797 | — |
| 反応物 | 1,3,5-Trihydroxyxanthone | HCID 5281663 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | 3,5-Di(2,3-epoxypropoxy)-1-hydroxyxanthone | HCID 10043806 | — |
反応手順
To a solution of 0.28 g (5.0 mmol) of potassium hydroxide in 3 ml of water was added 25 ml of 2-propanol and the 1.3 g (5.33 mmol) of 1,3,5-trihydroxyxanthone. To the above mixture was the added 7.5 ml (93.47 mmol) of epichlorohydrin, and the mixture was treated as example 4 to yield a pale yellow powder (MeOH) (21), 0.45 g (1.26 mmol, 35%)
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05981774 |
| 出典データセット | uspto-grants-1999_11 |
| ORD ID | ord-e02c57dca0d74373b6ceaa82ced71384 |
| 出典メモ | uspto-grants-1999_11 |