関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Allyl chloride | HCID 7850 | — |
| 反応物 | Diethoxydimethylsilane | HCID 62322 | — |
| 反応物 | 1,1-Diethenyl-1,3,3,3-tetramethyldisiloxane | HCID 17760531 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | Silane, (3-chloropropyl)dimethoxymethyl- | HCID 87491 | 19.7% |
反応手順
306 mg of allyl chloride, 530 mol of dimethyldiethoxysilane, and 77 mg of toluene were placed in a glass reaction tube. Then, 0.005 mol of a toluene solution of a 0-valent platinum complex of divinyltetramethyldisiloxane (platinum content: 0.4 wt %) was added to this mixture. The reaction tube was sealed and heated for 2 hours in an oil bath at 50° C. When the contents were analyzed by GC-MS following cooling, the conversion rate of allyl chloride was 100% and γ-chloropropylmethyldimethoxysilane was produced at a yield of 19.7%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05986124 |
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| 出典データセット | uspto-grants-1999_11 |
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| ORD ID | ord-d7dcaf5817964433b9e7492c9b503f1b |
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| 出典メモ | uspto-grants-1999_11 |
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