化工社化工社 化学情報印刷レポート · 研究参考用
Perillaldehyde → Perilla alcohol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Perillaldehyde | HCID 16441 | — |
| 反応物 | Selenium Dioxide | HCID 24007 | — |
| 反応物 | (+)-Limonene | HCID 440917 | — |
| 触媒 | chromium (VI) trioxide | HCID 10219390 | — |
| 生成物 | Perilla alcohol | HCID 369312 | — |
反応手順
Perillyl alcohol can be produced by reacting limonene with selenium dioxide (that is toxic) and other oxidants (that are difficult to work with i.e., anhydrous chromium trioxide) to yield various oxidation products, including a small amount of perillaldehyde. Once isolated, perillaldehyde is reduced to afford perillyl alcohol. While this two-step process is conceptually attractive, the oxidation of limonene to give perillyl alcohol proceeds in a low overall yield.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05994598 |
| 出典データセット | uspto-grants-1999_11 |
| ORD ID | ord-efc8b7b2544149a1a9a6fdf90618994b |
| 出典メモ | uspto-grants-1999_11 |