Oxygen → Hydroperoxide, phenylmethyl

HRID 1605124

反応式

HRID 1605124 の反応式
[O:1]=[O:2].[C:3]1([CH3:9])[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>>[CH2:9]([O:1][OH:2])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

参加物

3

反応物 2

HCID 977OxygenHCID 1140Toluene2 回

生成物 1

HCID 6451509Hydroperoxide, phenylmethyl

実験手順

750 G of toluene are introduced into a 1.5 liter stainless steel autoclave which is shaken; the toluene is oxidised, at 180°C under a pressure of 20 bars, with air depleted of oxygen until it contains only 8%, with an hourly flow rate of 240 liters (measured under normal temperature and pressure). After 1 hour 30 minutes the reaction mixture is cooled. The hydroperoxide is then purified via its sodium salt. 11.4 G of benzyl hydroperoxide, containing 85% by weight of pure product, are thus obtained.

後処理

  1. customis oxidised, at 180°C under a pressure of 20 bars, with air
  2. temperatureAfter 1 hour 30 minutes the reaction mixture is cooled
  3. customThe hydroperoxide is then purified via its sodium salt
  4. addition11.4 G of benzyl hydroperoxide, containing 85% by weight of pure product
  5. customare thus obtained

出典と根拠

ORDレコード
ord-8d465e630e6645a18cda1fa38fb4bfbb
出典データセット
uspto-grants-1976_04
特許番号
US03948995

関連ノート

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