3,4,5,6-Tetrabromophthalimide → N-(pentabromobenzoyl)-3,4,5,6-tetrabromophthalimide

HRID 1605208

反応式

HRID 1605208 の反応式
[K].[Br:2][C:3]1[C:13]([Br:14])=[C:12]([Br:15])[C:11]([Br:16])=[C:5]2[C:6]([NH:8][C:9](=[O:10])[C:4]=12)=[O:7].[Br:17][C:18]1[C:23]([C:24](Cl)=[O:25])=[C:22]([Br:27])[C:21]([Br:28])=[C:20]([Br:29])[C:19]=1[Br:30]>O1CCOCC1>[Br:17][C:18]1[C:23]([C:24]([N:8]2[C:9](=[O:10])[C:4]3=[C:3]([Br:2])[C:13]([Br:14])=[C:12]([Br:15])[C:11]([Br:16])=[C:5]3[C:6]2=[O:7])=[O:25])=[C:22]([Br:27])[C:21]([Br:28])=[C:20]([Br:29])[C:19]=1[Br:30]

参加物

5

反応物 3

HCID 904903,4,5,6-TetrabromophthalimideHCID 5462222PotassiumHCID 23051734Pentabromobenzoyl chloride

生成物 1

HCID 21546566N-(pentabromobenzoyl)-3,4,5,6-tetrabromophthalimide

試薬・触媒・溶媒 1

HCID 312751,4-Dioxane溶媒

実験手順

The potassium salt of 3,4,5,6-tetrabromophthalimide (0.10 mole) and dioxane (1200 ml) are charged into a glass reaction vessel equipped with a mechanical stirrer, thermometer and reflux condenser. Pentabromobenzoyl chloride (0.10 mole) is then added dropwise, with stirring, to the reaction mixture at room temperature. After the addition is completed the reaction mixture is heated at reflux for a period of about 1 hour. After this time the reaction mixture is filtered and the filtrate is stripped of solvent to yield the desired product N-(pentabromobenzoyl)-3,4,5,6-tetrabromophthalimide.

後処理

  1. customequipped with a mechanical stirrer
  2. temperaturethermometer and reflux condenser
  3. additionAfter the addition
  4. temperatureis heated
  5. temperatureat reflux for a period of about 1 hour
  6. filtrationAfter this time the reaction mixture is filtered

出典と根拠

ORDレコード
ord-465ddfbfd0a14159b0eaae470ed265ad
出典データセット
uspto-grants-1976_04
特許番号
US03950307

関連ノート

読み込み中…