4-Tert-octylphenol → 4-Tert-octylcatechol

HRID 1605629

反応式

HRID 1605629 の反応式
CCC(OO)=[O:4].[C:7]([C:15]1[CH:20]=[CH:19][C:18]([OH:21])=[CH:17][CH:16]=1)([CH2:10][C:11]([CH3:14])([CH3:13])[CH3:12])([CH3:9])[CH3:8]>CC(C)=O>[C:7]([C:15]1[CH:20]=[C:19]([OH:4])[C:18](=[CH:17][CH:16]=1)[OH:21])([CH2:10][C:11]([CH3:14])([CH3:13])[CH3:12])([CH3:8])[CH3:9]

参加物

4

反応物 2

HCID 88144-Tert-octylphenolHCID 65136Perpropionic acid

生成物 1

HCID 708284-Tert-octylcatechol収率 58%

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

The procedure of Example 9 was repeated, except 10.4g (0.1 mol) of perisobutyric acid in the form of about 20 weight% acetone solution was added over 30 minutes in place of perpropionic acid. Consequently, the conversion of para-tert.-octyl phenol was 13.2%, 4-tert.-octyl pyrocatechol was formed in a yield of 58% based on the converted octyl phenol and the conversion of perisobutyric acid was 100%.

出典と根拠

ORDレコード
ord-68b802726e934ca9a2f2937935a17169
出典データセット
uspto-grants-1976_04
特許番号
US03950437

関連ノート

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