Peracetic Acid → 4-Phenoxyphenol

HRID 1605634

反応式

HRID 1605634 の反応式
[C:1]1([O:7][C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(OO)(=[O:16])C>CC(C)=O>[CH:11]1[CH:10]=[CH:9][C:8]([O:7][C:1]2[C:2]([OH:16])=[CH:3][CH:4]=[CH:5][CH:6]=2)=[CH:13][CH:12]=1.[CH:11]1[CH:10]=[CH:9][C:8]([O:7][C:1]2[CH:2]=[CH:3][C:4]([OH:16])=[CH:5][CH:6]=2)=[CH:13][CH:12]=1

参加物

5

反応物 2

HCID 6585Peracetic AcidHCID 7583Diphenyl Ether2 回

生成物 2

HCID 132544-PhenoxyphenolHCID 754912-Hydroxydiphenyl ether

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

The procedure of Example 21 was repeated, except diphenyl ether was used in place of 4-methyl anisole and perisobutyric acid (used as 20% acetone solution) was used in place of peracetic acid. Consequently, the conversion of perisobutyric acid was 98.5%, the conversion of diphenyl ether was 8.28% and there were produced 4.15g of 2-hydroxydiphenyl ether and 2.04g of 4-hydroxydiphenyl ether.

出典と根拠

ORDレコード
ord-7ebac3570bb748048e6ac946c613918b
出典データセット
uspto-grants-1976_04
特許番号
US03950437

関連ノート

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