Benzene → (3-Ethyl-2-hydroxyphenyl)(phenyl)methanone

反応式

[CH:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[OH:7][C:8]1[C:16]([CH2:17][CH3:18])=[CH:15][CH:14]=[CH:13][C:9]=1[C:10](Cl)=[O:11]>>[OH:7][C:8]1[C:16]([CH2:17][CH3:18])=[CH:15][CH:14]=[CH:13][C:9]=1[C:10]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)=[O:11]

参加物

反応物 2

HCID 241Benzene

HCID 450815813-Ethyl-2-hydroxybenzoyl chloride

生成物 1

HCID 12562658(3-Ethyl-2-hydroxyphenyl)(phenyl)methanone収率 58.1%

実験手順

This compound (44.67g) was prepared from benzene (172g.,2.2 mole) and 2-hydroxy-3-ethyl benzoic acid chloride (63.15g,0.34 mole), using the same conditions as in Example 30. The b.p. of the compound was 123°-126°C./0.14mm, ηD22 1.6081,νmax.(film) 1630cm-1.

後処理

customwas 123°-126°C.

出典と根拠

ORDレコード: ord-ffda8fb0273d4c46a235d9c7a3e268e0
出典データセット: uspto-grants-1976_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US03951999

反応ノート

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