Hydrogen Peroxide → 3-Butylsulphinyl-1,2,4-triazole

HRID 1606060ノート

反応式

HRID 1606060 の反応式
[CH2:1]([S:5][C:6]1[N:10]=[CH:9][NH:8][N:7]=1)[CH2:2][CH2:3][CH3:4].[OH:11]O>C(O)(=O)C>[CH2:1]([S:5]([C:6]1[N:10]=[CH:9][NH:8][N:7]=1)=[O:11])[CH2:2][CH2:3][CH3:4]

参加物

4

反応物 2

HCID 784Hydrogen PeroxideHCID 178454955HCID 178454955、化合物

生成物 1

HCID 1784555543-Butylsulphinyl-1,2,4-triazole

試薬・触媒・溶媒 1

HCID 176Acetic Acid溶媒

実験手順

To a solution of 15.7 g. 3-butylthio-1,2,4-triazole in 60 ml. glacial acetic acid was added 100 vol. hydrogen peroxide solution (11.4 ml., 1 molecular proportion). The reaction mixture was cooled occasionally during 1 hour to maintain the reaction temperature at 25° - 30°C., and then kept at room temperature for 24 hours. The resulting solution was distilled under reduced pressure to produce a solid residue which was recrystallized from ethyl acetate to give 3-n-butylsulphinyl-1,2,4-triazole, m.p. 82° - 83°C.

後処理

  1. temperatureThe reaction mixture was cooled occasionally during 1 hour
  2. temperatureto maintain the reaction temperature at 25° - 30°C.
  3. distillationThe resulting solution was distilled under reduced pressure
  4. customto produce a solid residue which
  5. customwas recrystallized from ethyl acetate

出典と根拠

ORDレコード
ord-42e4655e89124dc2b2481e0603c25349
出典データセット
uspto-grants-1976_04
特許番号
US03952001

反応ノート

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