関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Diethyl Sulfate | HCID 6163 | — |
| 反応物 | O-ethyl N,N-diisobutyl-thiocarbamate | HCID 21542997 | — |
| 生成物 | Butylate | HCID 16181 | 92% |
反応手順
43.4 g. (0.2 mole) of O-ethyl N,N-diisobutyl-thiocarbamate are introduced into a 100 ml. round-bottomed flask, and 2.5 g. of diethyl sulfate are added. The mixture is refluxed for 90 minutes on an oil bath heated to 160°C, and thereafter the product is isolated by vacuum distillation. 39.8 g. (92 %) of S-ethyl N,N-diisobutyl-thiocarbamate are obtained; b.p.: 137°-138°C/20 Hgmm., nD25 = 1.4689.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US03953427 |
|---|
| 出典データセット | uspto-grants-1976_04 |
|---|
| ORD ID | ord-cd703b39e32d40d6a0aad0997c8a403a |
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| 出典メモ | uspto-grants-1976_04 |
|---|
