N,N-Dimethyltetradecylamine → Phenoxycarbonylmethyltetradecyldimethyl ammonium bromide
反応式
[Br:1][CH2:2][C:3]([O:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:4].[CH2:12]([N:26]([CH3:28])[CH3:27])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]>>[Br-:1].[O:5]([C:3]([CH2:2][N+:26]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])([CH3:27])[CH3:28])=[O:4])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1参加物
3
実験手順
A mixture of 55 g (0.26 mol) phenyl bromoacetate and 62 g (0.26 mol) of tetradecyldimethylamine was allowed to stand at room temperature for three days. The resultant crystalline mass was washed well with ether and dried to 114 g. Recrystallized from ethyl acetate and vacuum dried, the compound melted at 87°-91.5°.
後処理
- washThe resultant crystalline mass was washed well with ether
- customdried to 114 g
- customRecrystallized from ethyl acetate and vacuum
- customdried