Sodium Methoxide → HCID 19851157、化合物

HRID 1606857ノート

反応式

HRID 1606857 の反応式
[CH3:1][NH:2][C:3]1[CH:8]=[C:7](Cl)[CH:6]=[C:5]([NH:10][CH2:11][CH2:12][O:13][CH3:14])[C:4]=1[N+:15]([O-:17])=[O:16].[CH3:18][O-:19].[Na+]>CO>[CH3:1][NH:2][C:3]1[CH:8]=[C:7]([O:19][CH3:18])[CH:6]=[C:5]([NH:10][CH2:11][CH2:12][O:13][CH3:14])[C:4]=1[N+:15]([O-:17])=[O:16]

参加物

4

反応物 2

HCID 10942334Sodium MethoxideHCID 198511582-Methylamino-6-(beta-methoxyethyl)amino-4-chloronitrobenzene

生成物 1

HCID 19851157HCID 19851157、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

0.019 mole (5 g) of 2-methylamino-6-(β-methoxyethyl)amino-4-chloronitrobenzene was refluxed with 35 ml of 26% sodium methylate in methanol for 45 minutes then diluted with 100 ml of ice water to precipitate the desired product. Following filtering, water washing and drying under vacuum in the presence of P2O5, the product obtained was recrystallized from isopropanol. It melted at 84° C.

後処理

  1. customto precipitate the desired product
  2. filtrationFollowing filtering
  3. dry with materialwater washing and drying under vacuum in the presence of P2O5
  4. customthe product obtained
  5. customwas recrystallized from isopropanol

出典と根拠

ORDレコード
ord-d58a90feab3246739159828477f4c590
出典データセット
uspto-grants-1989_09
特許番号
US04863482

反応ノート

読み込み中…