化工社化工社 化学情報印刷レポート · 研究参考用
Water → 4-Methylthio-3-(trifluoromethyl)phenylboronic acid pinacol ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Diethyl Ether | HCID 3283 | — |
| 反応物 | Pinacol | HCID 6425 | — |
| 反応物 | 4-Methylthio-3-(trifluoromethyl)phenylboronic acid | HCID 74891169 | — |
| 溶媒 | 1,4-Dioxane | HCID 31275 | — |
| 生成物 | 4-Methylthio-3-(trifluoromethyl)phenylboronic acid pinacol ester | HCID 67277301 | — |
反応手順
The product of step b) (0.25 g) was heated in dioxan (2 ml) with pinacol (2 equiv) for 3 h. The solution was treated with diethyl ether and water. The organic layer was separated, washed with brine, dried (Na2SO4) and concentrated in vacuo. Yield 85 mg.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07737135B2 |
| 出典データセット | uspto-grants-2010_06 |
| ORD ID | ord-4377e4d71b804528910e589e09a43d88 |
| 出典メモ | uspto-grants-2010_06 |