化工社化工社 化学情報印刷レポート · 研究参考用
Allyl Alcohol → (3-Allyl-)heptafluorobutan-2-one
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Allyl Alcohol | HCID 7858 | — |
| 反応物 | 1,1,1,2,3,4,4,4-Octafluorobut-2-ene | HCID 9678 | — |
| 反応物 | Potassium Hydroxide | HCID 14797 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | (3-Allyl-)heptafluorobutan-2-one | HCID 22074693 | — |
反応手順
396 g (1.98 mol) of octafluorobut-2-ene is condensed into 116 g (2 mol) of allyl alcohol at -5° C. Then 113 g (1.98 mol) of KOH, dissolved in 150 ml of water, is slowly added dropwise over the course of 3 hours, the temperature being maintained at 0°-5° C. Stirring continues overnight at room temperature and working-up is performed in the same way as in Example 2a.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05399645 |
| 出典データセット | uspto-grants-1995_03 |
| ORD ID | ord-5344c9fec59d4d58975ffa741fb2bfb6 |
| 出典メモ | uspto-grants-1995_03 |