Diethyl Ether → HCID 22237792、化合物
反応式
[CH3:1][C:2]1[C:3]([CH3:12])([CH3:11])[C:4]2[CH:10]=[CH:9][CH:8]=[CH:7][C:5]=2[N:6]=1.[C:13]([O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][I:22])(=[O:15])[CH3:14].CCOCC>ClC1C=CC=CC=1Cl>[I-:22].[CH3:1][C:2]1[C:3]([CH3:12])([CH3:11])[C:4]2[CH:10]=[CH:9][CH:8]=[CH:7][C:5]=2[N+:6]=1[CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][O:16][C:13]([CH3:14])=[O:15]参加物
5
反応条件
- 温度
- 120 °C
実験手順
A mixture of 2,3,3-trimethyl-3H-benzo[b]azole (2.39 g, 15 mmol) and 5-iodopentyl acetate (3.84 g, 15 mmol) in 1,2-dichlorobenzene (15 ml) were heated at 120° C. for 6 h and then cooled to ambient temperature. The mixture was then dripped into Et2O which precipitated the title compound as a red gum which was collected and used without any further purification in subsequent reactions.