Quinoline → (Z)-dodec-2-en-1-ol

HRID 1612799ノート

反応式

HRID 1612799 の反応式
C(O)/C=C\CCCCCCC.[CH2:12]([OH:24])[C:13]#[C:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23].N1C2C(=CC=CC=2)C=CC=1>>[CH2:12]([OH:24])/[CH:13]=[CH:14]\[CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH3:23]

参加物

4

反応物 3

HCID 7047QuinolineHCID 1712322Dodec-2-yn-1-olHCID 53649532-Decen-1-ol, (Z)-

生成物 1

HCID 5364955(Z)-dodec-2-en-1-ol

実験手順

cis-2-Dodecen-1-ol was prepared as described above for cis-2-decen-1-ol except that 35 g of 2-dodecyn-1-ol, 1.0 g of catalyst, and 3.0 ml of quinoline was used. A clear oil, 33.86 g, was obtained after kugelrohr distillation. 1H NMR δ5.57 (m, 2), 4.19 (d, 2, J=5 Hz), 2.07 (dd, 2, J=6, 12 Hz), 1.5-1.2 (m, 14), 0.88 (t, 3, J=7 HZ).

後処理

  1. customA clear oil, 33.86 g, was obtained
  2. distillationafter kugelrohr distillation

出典と根拠

ORDレコード
ord-29c445e10cd84eda8e1d41d37cdfb73e
出典データセット
uspto-grants-1993_03
特許番号
US05190969

反応ノート

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