Hydrochloric Acid → Zirconium(IV) sulfate

反応式

[S:1]([O-:5])([O-:4])(=[O:3])=[O:2].[Na+].[Na+].O(Cl)Cl.[Zr:11].Cl>>[S:1]([O-:5])([O-:4])(=[O:3])=[O:2].[Zr+4:11].[S:1]([O-:5])([O-:4])(=[O:3])=[O:2]

参加物

反応物 3

HCID 313Hydrochloric Acid

HCID 24436Sodium Sulfate

HCID 71304769Chloro hypochlorite;zirconium

生成物 1

HCID 26793Zirconium(IV) sulfate

反応条件

温度: 85 °C

実験手順

141 g of a 25% sodium sulfate solution was heated to 85° C. Then, 375 g of a zirconium oxychloride solution containing 16% of ZrO2 equivalent, previously heated to 85° C., was added thereto. Thereafter, hydrochloric acid was added so that the free acid concentration became 1.5; N, and the resulting product was maintained for 0.5 hour to form basic zirconium sulfate.