Benzoyl chloride → N-benzoyl-5-formyl-6-methoxy-3'-nitro-biphenyl-3-sulfonamide

反応式

[CH:1]([C:3]1[CH:4]=[C:5]([S:20]([NH2:23])(=[O:22])=[O:21])[CH:6]=[C:7]([C:11]2[CH:16]=[CH:15][CH:14]=[C:13]([N+:17]([O-:19])=[O:18])[CH:12]=2)[C:8]=1[O:9][CH3:10])=[O:2].[C:24](Cl)(=[O:31])[C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1>>[C:24]([NH:23][S:20]([C:5]1[CH:6]=[C:7]([C:11]2[CH:16]=[CH:15][CH:14]=[C:13]([N+:17]([O-:19])=[O:18])[CH:12]=2)[C:8]([O:9][CH3:10])=[C:3]([CH:1]=[O:2])[CH:4]=1)(=[O:22])=[O:21])(=[O:31])[C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1

参加物

反応物 2

HCID 7412Benzoyl chloride

HCID 866077105-Formyl-6-methoxy-3'-nitro-biphenyl-3-sulfonamide

生成物 1

HCID 86607722N-benzoyl-5-formyl-6-methoxy-3'-nitro-biphenyl-3-sulfonamide

実験手順

Proceeding as in Reference 21, but substituting 5-formyl-6-methoxy-3′-nitro-biphenyl-3-sulfonamide and benzoyl chloride, gave N-benzoyl-5-formyl-6-methoxy-3′-nitro-biphenyl-3-sulfonamide.

出典と根拠

ORDレコード: ord-065dbda7f42a4a6d90690aafbecff289
出典データセット: uspto-grants-2014_07
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08778625B2

反応ノート

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