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3-(Tributylstannyl)pyridine → 1-(beta-D-glucopyranosyl)-4-chloro-3-(5-(3-pyridyl)-2-thienylmethyl)benzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 3-(Tributylstannyl)pyridine | HCID 3483848 | — |
| 反応物 | 1-(2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl)-4-chloro-3-(5-chloro-2-thienylmethyl)benzene | HCID 66608207 | — |
| 生成物 | 1-(beta-D-glucopyranosyl)-4-chloro-3-(5-(3-pyridyl)-2-thienylmethyl)benzene | HCID 69624867 | — |
反応手順
The above 1-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-4-chloro-3-(5-chloro-2-thienylmethyl)benzene and tri-n-butyl(3-pyridyl)tin were used and treated in a manner similar to Example 124 to give the target compound as colorless powder. APCI-Mass m/Z 448/450 (M+H).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08785403B2 |
| 出典データセット | uspto-grants-2014_07 |
| ORD ID | ord-9b099624a5eb45379ac45c2c61254504 |
| 出典メモ | uspto-grants-2014_07 |