2-Bromothiophene → 2-(3-methylphenyl)thiophene

反応式

Br[C:2]1[S:3][CH:4]=[CH:5][CH:6]=1.[CH3:7][C:8]1[CH:9]=[C:10](B(O)O)[CH:11]=[CH:12][CH:13]=1>>[CH3:7][C:8]1[CH:13]=[C:12]([C:2]2[S:3][CH:4]=[CH:5][CH:6]=2)[CH:11]=[CH:10][CH:9]=1

参加物

反応物 2

HCID 138512-Bromothiophene

HCID 27339503-Tolylboronic acid

生成物 1

HCID 35641882-(3-methylphenyl)thiophene

実験手順

2-Bromothiophene and 3-methylphenylboronic acid were treated in a manner similar to Reference Example 26-(2) to give 2-(3-methylphenyl)thiophene as colorless oil.

出典と根拠

ORDレコード: ord-d0fb186ef9034c9089a2ec92ef9c7e75
出典データセット: uspto-grants-2014_07
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08785403B2

反応ノート

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