Triacetoxyperiodinane → HCID 86670633、化合物
反応式
[C:1]1([C:7]2[N:8]([C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)[C:9]3[C:14]([N:15]=2)=[C:13]([NH:16][CH2:17][CH2:18][CH2:19][OH:20])[N:12]=[CH:11][N:10]=3)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.CC(OI1(OC(C)=O)(OC(C)=O)OC(=O)C2C=CC=CC1=2)=O>ClCCl>[C:1]1([C:7]2[N:8]([C:21]3[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=3)[C:9]3[C:14]([N:15]=2)=[C:13]([NH:16][CH2:17][CH2:18][CH:19]=[O:20])[N:12]=[CH:11][N:10]=3)[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1参加物
4
実験手順
To the solution of 3-(8,9-diphenyl-9H-purin-6-ylamino)propan-1-ol obtained in step 1 (0.77 g, 2.24 mmol) in dichloromethane was added Dess-Martin (1.4 g, 3.37 mmol) at room temperature and stirred for 2 hours at room temperature. The resulting reaction mixture was concentrated under reduced pressure. The residue was diluted with CH2Cl2, and washed with water. The organic layer thus separated was dried over anhydrous MgSO4 and evaporated in vacuo to provide title compound (0.73 g, 94%) as yellow solid.