Tert-Butylamine → N-(1,1-dimethylethyl)-1,1-dimethyl-1-(1,5,6,7-tetrahydro-2-methyl-3-phenyl-s-indacen-1-yl)silanamine

HRID 1636216ノート

反応式

HRID 1636216 の反応式
Cl[Si:2]([CH3:23])([CH3:22])[CH:3]1[C:14]2[C:6](=[CH:7][C:8]3[CH2:9][CH2:10][CH2:11][C:12]=3[CH:13]=2)[C:5]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[C:4]1[CH3:21].CCN(CC)CC.[C:31]([NH2:35])([CH3:34])([CH3:33])[CH3:32]>CCCCCC>[CH3:32][C:31]([NH:35][Si:2]([CH3:23])([CH3:22])[CH:3]1[C:14]2[C:6](=[CH:7][C:8]3[CH2:9][CH2:10][CH2:11][C:12]=3[CH:13]=2)[C:5]([C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[C:4]1[CH3:21])([CH3:34])[CH3:33]

参加物

5

反応物 3

HCID 6385Tert-ButylamineHCID 8471TriethylamineHCID 19350461Chlorodimethyl(1,5,6,7-tetrahydro-2-methyl-3-phenyl-s-indacen-1-yl) silane

生成物 1

HCID 19350467N-(1,1-dimethylethyl)-1,1-dimethyl-1-(1,5,6,7-tetrahydro-2-methyl-3-phenyl-s-indacen-1-yl)silanamine収率 91.3%

試薬・触媒・溶媒 1

HCID 8058Hexane溶媒

実験手順

Chlorodimethyl(1,5,6,7-tetrahydro-2-methyl-3-phenyl-s-indacen-1-yl)silane (5.3483 g, 0.01578 moles) was stirred in hexane (100 mL) as NEt3 (2.2579 g, 0.02231 moles) and t-butylamine (1.9898 g, 0.02721 moles) were added. This mixture was allowed to stir for 24 hours. After the reaction period the mixture was filtered and the volatiles removed resulting in the isolation of the desired product as a yellow oil (5.4118 g, 91.3 percent).

後処理

  1. additionwere added
  2. customAfter the reaction period the mixture
  3. filtrationwas filtered
  4. customthe volatiles removed

出典と根拠

ORDレコード
ord-cebc1474b04d49658d0055457fa0bd34
出典データセット
uspto-grants-2000_03
特許番号
US06034022

反応ノート

読み込み中…