Sodium Acetate → HCID 86743506、化合物

HRID 1638734ノート

反応式

HRID 1638734 の反応式
O.[Br:2][C:3]1[CH:4]=[C:5]([C:9]([CH:11]=O)=[O:10])[CH:6]=[CH:7][CH:8]=1.Cl.[CH3:14][O:15][C:16]1[CH:21]=[CH:20][C:19]([CH2:22][CH:23]([NH:25][OH:26])[CH3:24])=[CH:18][CH:17]=1.C([O-])(=O)C.[Na+]>CO>[Br:2][C:3]1[CH:4]=[C:5]([CH:6]=[CH:7][CH:8]=1)[C:9]([CH:11]=[N+:25]([CH:23]([CH3:24])[CH2:22][C:19]1[CH:20]=[CH:21][C:16]([O:15][CH3:14])=[CH:17][CH:18]=1)[O-:26])=[O:10]

参加物

5

反応物 3

HCID 517045Sodium AcetateHCID 1407493892188-54-0HCID 140749403-Bromophenylglyoxal hydrate

生成物 1

HCID 86743506HCID 86743506、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

2.31 g (10 mmol) of 3-bromophenylglyoxal hydrate, 2.175 g (20 mmol) of N-(2-(4-methoxyphenyl)-1-methylethyl)hydroxylamine hydrochloride and 820 mg (10 mmol) of sodium acetate were stirred in 50 ml of absolute methanol at room temperature for 4 hours. After filtration, the fitrate was evaporated, 50 ml of water were added to the residue and the mixture was extracted with methylene chloride (3×25 ml).

後処理

  1. filtrationAfter filtration
  2. customthe fitrate was evaporated
  3. addition50 ml of water were added to the residue
  4. extractionthe mixture was extracted with methylene chloride (3×25 ml)

出典と根拠

ORDレコード
ord-616b27466629452a9e8c8bcadfff8aa6
出典データセット
uspto-grants-1989_11
特許番号
US04880840

反応ノート

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