Benzyl Chloride → Dibenzyl sulfide

HRID 1638766ノート

反応式

HRID 1638766 の反応式
O.O.O.O.O.O.O.O.O.[S-2:10].[Na+].[Na+].[CH2:13](Cl)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>O>[CH2:13]([S:10][CH2:13][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

参加物

4

反応物 2

HCID 7503Benzyl ChlorideHCID 73972Sodium sulfide nonahydrate

生成物 1

HCID 10867Dibenzyl sulfide収率 188.5%

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

Sodium sulphide nonahydrate (2.40 g, 0.01 mol), benzyl chloride (1.26 g, 0.01 mol), water (3 ml) and compound 1 (0.5 mmol) were stirred at 70°-78° C. for 20 minutes. The reaction mixture was poured into water and left overnight at room temperature. The white crystals thus obtained were filtered off and dried to give 2.02 g of benzyl sulphide.

後処理

  1. customThe white crystals thus obtained
  2. filtrationwere filtered off
  3. customdried

出典と根拠

ORDレコード
ord-1d2a958485814bccb29f50f62fb0ee9c
出典データセット
uspto-grants-1989_11
特許番号
US04880894

反応ノート

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