1-(Hexyloxy)-2-nitrobenzene → 2-(Hexyloxy)aniline

HRID 1639114ノート

反応式

HRID 1639114 の反応式
[CH2:1]([O:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[N+:14]([O-])=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[H][H]>CO.[Ni]>[CH2:1]([O:7][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][C:9]=1[NH2:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

参加物

5

反応物 2

HCID 150681131-(Hexyloxy)-2-nitrobenzeneHCID 178418361HCID 178418361、化合物2 回

生成物 1

HCID 159374522-(Hexyloxy)aniline

試薬・触媒・溶媒 2

HCID 935Nickel触媒HCID 887Methanol溶媒

実験手順

1-(Hexyloxy)-2-nitrobenzene, 61.28 g (0.27 mol) is dissolved in 700 ml of methanol, 3 g Raney nickel is added and the mixture exposed to hydrogen gas until the required amount of hydrogen is absorbed. The methanol solution is filtered and concentrated in vacuo and the residue distilled to give 50 g of 2-(hexyloxy)benzenamine; bp 145°-148° C. at 4 mm.

後処理

  1. customis absorbed
  2. filtrationThe methanol solution is filtered
  3. concentrationconcentrated in vacuo
  4. distillationthe residue distilled

出典と根拠

ORDレコード
ord-0280dc5bb5ee423ab0767d93426a37c5
出典データセット
uspto-grants-1989_11
特許番号
US04882357

反応ノート

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