(R)alpha-methyl-3-phenoxy-benzyl (IR,cis) 2,2-dimethyl-3-[(Z) 3-hydroxy-3-oxo-1-propenyl]-cyclopropane-carboxylate → (R)alpha-methyl-3-phenoxy-benzyl (IR,cis) 2,2-dimethyl-3-[(Z) 3-oxo-3-(2-methoxyethoxy)-1-propenyl]-cyclopropane-carboxylate
反応式
[CH3:1][C:2]1([CH3:28])[C@@H:4](/[CH:5]=[CH:6]\[C:7]([OH:9])=[O:8])[C@H:3]1[C:10]([O:12][C@H:13]([CH3:27])[C:14]1[CH:19]=[CH:18][CH:17]=[C:16]([O:20][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)[CH:15]=1)=[O:11]>COCCO>[CH3:1][C:2]1([CH3:28])[C@@H:4](/[CH:5]=[CH:6]\[C:7](=[O:9])[O:8][CH2:3][CH2:10][O:12][CH3:13])[C@H:3]1[C:10]([O:12][C@H:13]([CH3:27])[C:14]1[CH:19]=[CH:18][CH:17]=[C:16]([O:20][C:21]2[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=2)[CH:15]=1)=[O:11]参加物
3
反応物 1
生成物 1
試薬・触媒・溶媒 1
実験手順
The product of Step C was reacted with 2-methoxyethanol to obtain (R)α-methyl-3-phenoxy-benzyl (IR,cis) 2,2-dimethyl-3-[(Z) 3-oxo-3-(2-methoxyethoxy)-1-propenyl]-cyclopropane-carboxylate.