Methyl Palmitate → 1-Tetradecene
反応式
[C:1](OC)(=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14]CC>CCCCCC>[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]参加物
3
試薬・触媒・溶媒 1
実験手順
Irradiation of methyl palmitate. Methyl palmitate was dissolved in a small amount of hexane and irradiated in a quartz container (UV cuvette) at 253.7 nm in the Rayonet reactor. After 7 hours a small amount of 1-tetradecene was formed. After 24 hours a larger amount of 1-tetradecene and a corresponding isomer (to be identified but likely 2-tetradecene (CH3CH═CHCH2(CH2)9CH3) was obtained.
出典と根拠
- ORDレコード
- ord-65eed43cf6744f63b32103934bf27a48
- 出典データセット
- uspto-grants-2012_02
- 特許番号
- US08110074B1
反応ノート
読み込み中…