N,N-bis(1H-benzimidazol-2-ylmethyl)-N-benzylamine chromium (III) chloride → N,N-bis(1H-benzimidazol-2-ylmethyl)-N-benzylamine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

HRID 1645213ノート

反応式

HRID 1645213 の反応式
[O:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[F:6][Sb-:7]([F:12])([F:11])([F:10])([F:9])[F:8].[Cl-:13].[Cr+3:14].N1C2C=CC=CC=2N=C1CNCC1NC2C=CC=CC=2N=1.[Cl-].[Cr+3].[NH:38]1[C:42]2[CH:43]=[CH:44][CH:45]=[CH:46][C:41]=2[N:40]=[C:39]1[CH2:47][N:48]([CH2:56][C:57]1[NH:61][C:60]2[CH:62]=[CH:63][CH:64]=[CH:65][C:59]=2[N:58]=1)[CH2:49][C:50]1[CH:55]=[CH:54][CH:53]=[CH:52][CH:51]=1.[Cl-].[Cl-]>F[Sb-](F)(F)(F)(F)F.[Ag+]>[O:1]1[CH2:5][CH2:4][CH2:3][CH2:2]1.[F:6][Sb-:7]([F:12])([F:11])([F:10])([F:9])[F:8].[Cl-:13].[Cr+3:14].[NH:38]1[C:42]2[CH:43]=[CH:44][CH:45]=[CH:46][C:41]=2[N:40]=[C:39]1[CH2:47][N:48]([CH2:56][C:57]1[NH:58][C:59]2[CH:65]=[CH:64][CH:63]=[CH:62][C:60]=2[N:61]=1)[CH2:49][C:50]1[CH:55]=[CH:54][CH:53]=[CH:52][CH:51]=1

参加物

4

反応物 2

HCID 86638462N,N-bis(1H-benzimidazol-2-ylmethyl)-N-benzylamine chromium (III) chlorideHCID 86638469N,N-bis(1H-benzimidazol-2-ylmethyl)amine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

生成物 1

HCID 86638470N,N-bis(1H-benzimidazol-2-ylmethyl)-N-benzylamine chromium (III) chloride hexafluoroantimonate tetrahydrofuran

試薬・触媒・溶媒 1

HCID 16687962Silver hexafluoroantimonate触媒

実験手順

4d was synthesised by an analogous procedure to that described for 4a using silver hexafluoroantimonate (0.20 g, 0.57 mmol) and complex 3d (0.30 g, 0.57 mmol). Yield 0.31 g, 68%. +FAB-MS: (m/e): 489 ([M]+), 454 ([M-Cl]+). −FAB-MS: (m/z): 235 ([M]−).

出典と根拠

ORDレコード
ord-a1b2b7bf60704172a50648da50812bc5
出典データセット
uspto-grants-2012_02
特許番号
US08124698B2

反応ノート

読み込み中…