Formic Acid → HCID 19738514、化合物

HRID 1646026ノート

反応式

HRID 1646026 の反応式
[F:1][CH2:2][C:3](=[CH2:17])[CH2:4][N:5]([CH2:11][CH:12](OC)[O:13]C)[C:6](=[O:10])[O:7][CH2:8][CH3:9].C(O)=O.[Cl-].[Na+]>O>[F:1][CH2:2][C:3](=[CH2:17])[CH2:4][N:5]([CH2:11][CH:12]=[O:13])[C:6](=[O:10])[O:7][CH2:8][CH3:9]

参加物

5

反応物 3

HCID 284Formic AcidHCID 5234Sodium ChlorideHCID 19738525HCID 19738525、化合物

生成物 1

HCID 19738514HCID 19738514、化合物

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

25 g (0.1 mol) of ethyl N-(2-fluoromethylallyl)-N-(2,2-dimethoxyethyl)carbamate are heated under reflux for two hours with 5 g of formic acid in 100 ml of water. The mixture is saturated with sodium chloride and extracted with methylene chloride, and the organic phases are washed with sodium hydrogen carbonate solution until neutral. They are dried over magnesium sulphate and concentrated, and the residue is distilled.

後処理

  1. extractionextracted with methylene chloride
  2. washthe organic phases are washed with sodium hydrogen carbonate solution until neutral
  3. dry with materialThey are dried over magnesium sulphate
  4. concentrationconcentrated
  5. distillationthe residue is distilled

出典と根拠

ORDレコード
ord-73374681134148b4adf611c6c912feaa
出典データセット
uspto-grants-1993_01
特許番号
US05177210

反応ノート

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