O-Xylene → HCID 15376513、化合物
反応式
[C:1]1([C:7]2[C:8](=O)[O:9][C:10](C)(C)[O:11][CH:12]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C=[N:17][C:18]([CH3:26])([C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)[CH3:19].[C:27]1(C)C(C)=CC=CC=1>>[CH3:27][C:8]1[O:9][CH2:10][N:17]([C:18]([CH3:26])([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH3:19])[C:12](=[O:11])[C:7]=1[C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1参加物
4
実験手順
Xylene (2 ml) was added to a mixture of 5-phenyl-2,2-dimethyl-2H,4H-1,3-dioxin-4-one (0.82 g) and N-methylene-1-methyl-1-phenylethylamine (0.59 g), and the resulting mixture was heated at reflux for 20 minutes for reaction. The reaction mixture was purified by silica gel chromatography to obtain the captioned compound (0.9 g).
後処理
- temperaturethe resulting mixture was heated
- temperatureat reflux for 20 minutes for reaction
- customThe reaction mixture was purified by silica gel chromatography