Ammonia → HCID 19919896、化合物
反応式
Cl.[CH2:2]1[C:13]2=[C:14]3[C:9](=[CH:10][CH:11]=[CH:12]2)[CH:8]=[CH:7][CH:6]=[C:5]3[CH2:4][C:3]1=O.[C-:16]#[N:17].[Na+].[NH3:19]>O.C(OCC)C>[NH2:19][C:3]1([C:16]#[N:17])[CH2:4][C:5]2[C:14]3[C:9]([CH:8]=[CH:7][CH:6]=2)=[CH:10][CH:11]=[CH:12][C:13]=3[CH2:2]1参加物
7
実験手順
1 ml of concentrated hydrochloric acid is added dropwise to a vigorously stirred mixture of 13.7 mmol of 1,3-dihydro-2-phenalenone and 40 mmol of sodium cyanide in 60 ml of water and 80 ml of ethyl ether. After one hour of stirring at 20C., and when settling has taken place, the organic phase is separated, washed with water, dried and evaporated. The residue obtained is treated with 20 ml of a methanolic solution of ammonia (3.5M) with stirring for 5 hours at 20C.
後処理
- customthe organic phase is separated
- washwashed with water
- customdried
- customevaporated
- customThe residue obtained
出典と根拠
- ORDレコード
- ord-6ab4fa6ffcbc4c75b526d10339dd8ab9
- 出典データセット
- uspto-grants-1995_07
- 特許番号
- US05436261
反応ノート
読み込み中…