関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 9-Anthracenecarboxylic acid | HCID 2201 | — |
| 反応物 | Glycidyl methacrylate | HCID 7837 | — |
| 反応物 | 2,6-Di-tert-butyl-4-methylphenol | HCID 31404 | — |
| 触媒 | Tetramethylammonium chloride | HCID 6379 | — |
| 生成物 | 3-(Methacryloyloxy)-2-hydroxypropyl anthracene-9-carboxylate | HCID 54531280 | — |
反応手順
Anthracene-9-carboxylic acid (50 g) was added over 30 minutes with stirring to glycidyl methacrylate (33.9 g, epoxide content 6.6 equiv./kg) containing 0.13 g of 2,6-di-tert.butyl-p-cresol and 0.25 g of tetramethylammonium chloride and heated to 100° C. Heating at 100° C. was continued for a further 4 hours, by which time the epoxide content of the mixture had fallen to a negligibly low value. The resultant product was a brown, glassy solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04413052 |
|---|
| 出典データセット | uspto-grants-1983_11 |
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| ORD ID | ord-e544f4574f9a4608bc2bd891f9a1fe9c |
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| 出典メモ | uspto-grants-1983_11 |
|---|
