Triethylamine → Methylthiomethyl Geranate

HRID 1648907ノート

反応式

HRID 1648907 の反応式
[C:1]([OH:12])(=[O:11])/[CH:2]=[C:3](/[CH2:5][CH2:6][CH:7]=[C:8]([CH3:10])[CH3:9])\[CH3:4].[CH3:13][S:14][CH2:15]Cl.C(N(CC)CC)C>>[C:1]([O:12][CH2:13][S:14][CH3:15])(=[O:11])/[CH:2]=[C:3](/[CH2:5][CH2:6][CH:7]=[C:8]([CH3:9])[CH3:10])\[CH3:4]

参加物

4

反応物 3

HCID 8471TriethylamineHCID 16916Chloromethyl methyl sulfideHCID 5275520Geranic acid

生成物 1

HCID 86738396Methylthiomethyl Geranate

実験手順

This product was prepared according to the procedure described in Example 1, by reacting geranic acid with chloromethyl methyl sulfide in the presence of one equivalent of triethylamine; b.p. 111°-112° C./2 mm Hg, n20 1.4912.

後処理

  1. customThis product was prepared

出典と根拠

ORDレコード
ord-71fbd4cf77f74978b6eb177cb7227d38
出典データセット
uspto-grants-1983_11
特許番号
US04414233

反応ノート

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