ethyl 6-benzyl-5,6,7,8-tetrahydro-4H-thieno[2,3-d]azepine-2-carboxylate → HCID 13072040、化合物

HRID 1648935ノート

反応式

HRID 1648935 の反応式
[CH2:1]([N:8]1[CH2:14][CH2:13][C:12]2[CH:15]=[C:16]([C:18]([O:20][CH2:21][CH3:22])=[O:19])[S:17][C:11]=2[CH2:10][CH2:9]1)[C:2]1C=CC=CC=1>[Ni].C(O)C>[CH2:1]([N:8]1[CH2:14][CH2:13][C:12]2[CH:15]=[C:16]([C:18]([O:20][CH2:21][CH3:22])=[O:19])[S:17][C:11]=2[CH2:10][CH2:9]1)[CH3:2]

参加物

4

反応物 1

HCID 13072038ethyl 6-benzyl-5,6,7,8-tetrahydro-4H-thieno[2,3-d]azepine-2-carboxylate

生成物 1

HCID 13072040HCID 13072040、化合物

試薬・触媒・溶媒 2

HCID 935Nickel触媒HCID 702Ethanol溶媒

実験手順

3.15 gm (0.01 mol) of ethyl 6-benzyl-5,6,7,8-tetrahydro-4H-thieno[2,3-d]azepine-2-carboxylate were refluxed with the same amount of Raney nickel in 50 ml of ethyl alcohol for 6 hours. The catalyst was then removed by suction filtering, and the filtrate was concentrated by evaporation.

後処理

  1. customThe catalyst was then removed by suction
  2. filtrationfiltering
  3. concentrationthe filtrate was concentrated by evaporation

出典と根拠

ORDレコード
ord-024c7012f65d4a58a5092da722aa51a2
出典データセット
uspto-grants-1983_11
特許番号
US04414225

反応ノート

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