tert-Butyl 4-benzoylbenzene-1-carboperoxoate → Tert-butyl-4-(4'-methoxybenzoyl)perbenzoate

HRID 1649334ノート

反応式

HRID 1649334 の反応式
[C:1]([O:5][O:6][C:7](=[O:22])[C:8]1[CH:13]=[CH:12][C:11]([C:14](=[O:21])[C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[CH:10][CH:9]=1)([CH3:4])([CH3:3])[CH3:2].[CH3:23][O:24]C1C=CC(C(C2C=CC(C(O)=O)=CC=2)=O)=CC=1>CCOCC.ClCCl>[C:1]([O:5][O:6][C:7](=[O:22])[C:8]1[CH:13]=[CH:12][C:11]([C:14](=[O:21])[C:15]2[CH:20]=[CH:19][C:18]([O:24][CH3:23])=[CH:17][CH:16]=2)=[CH:10][CH:9]=1)([CH3:4])([CH3:2])[CH3:3]

参加物

5

反応物 2

HCID 13494638tert-Butyl 4-benzoylbenzene-1-carboperoxoateHCID 177891814-(4-Methoxybenzoyl)benzoic acid

生成物 1

HCID 20427249Tert-butyl-4-(4'-methoxybenzoyl)perbenzoate

試薬・触媒・溶媒 2

HCID 3283Diethyl Ether溶媒HCID 6344Dichloromethane溶媒

実験手順

Tert-butyl-4-(4'-methoxybenzoyl)perbenzoate is prepared by the above discussed procedure for the preparation of t-butyl-4-benzoylperbenzoate, except that the acid employed is 4-(4'-methoxybenzoyl)-benzoic acid, and during the preparation, the corresponding acid chloride is dissolved in a mixture of ether and dichloromethane.

後処理

  1. customduring the preparation

出典と根拠

ORDレコード
ord-42394d99e7b444b48082b6568f0c284f
出典データセット
uspto-grants-1983_11
特許番号
US04416826

反応ノート

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