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Phosphorus oxychloride → 2-Methoxy-10-(5-methyl-1-pyrrolin-2-YL)phenoxazine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Phosphorus oxychloride | HCID 24813 | — |
| 反応物 | 5-Methyl-2-pyrrolidone | HCID 66055 | — |
| 反応物 | 2-Methoxyphenoxazine | HCID 22754303 | — |
| 生成物 | 2-Methoxy-10-(5-methyl-1-pyrrolin-2-YL)phenoxazine | HCID 22754310 | — |
反応手順
Reaction of 2-methoxyphenoxazine, 5-methyl-2-pyrrolidinone and phosphorus oxychloride according to the procedure of Example 1 provides the free base 2-METHOXY-10-(5-METHYL-1-PYRROLIN-2YL)PHENOXAZINE as an oil. Conversion of the free base to the hydrochloride salt affords 2METHOXY-10-(5-METHYL-1-PYRROLIN-2-YL)-PHENOXAZINE HYDROCHLORIDE, m.p. 223.5°-224.5°C. (dec.)(corr.), as the hemihydrate by trituration with acetone.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US03962252 |
| 出典データセット | uspto-grants-1976_06 |
| ORD ID | ord-c7911eba956245d8b915812d96c29385 |
| 出典メモ | uspto-grants-1976_06 |