3-Pyridinemethanol → (Pyridin-3-yl)methyl (4-sulfanylphenyl)carbamate
反応式
[SH:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]=[C:9]=[O:10])=[CH:4][CH:3]=1.[N:11]1[CH:16]=[CH:15][CH:14]=[C:13]([CH2:17][OH:18])[CH:12]=1>C1C=CC=CC=1>[SH:1][C:2]1[CH:7]=[CH:6][C:5]([NH:8][C:9](=[O:10])[O:18][CH2:17][C:13]2[CH:12]=[N:11][CH:16]=[CH:15][CH:14]=2)=[CH:4][CH:3]=1参加物
4
実験手順
p-Mercaptophenyl isocyanate (0.9g., 0.00595 mole) was added to a solution of 3-pyridyl carbinol (0.65g., 0.00595 mole) in 50 ml. of benzene and the reaction mixture was allowed to stand over the weekend. It was then heated to reflux to assure completion of the reaction and then cooled to give a white solid. This was isolated as 1.2g. and was a 78% yield of 3-pyridylmethyl N-(4'-mercaptophenyl)carbamate.
後処理
- temperatureIt was then heated
- temperatureto reflux
- customcompletion of the reaction
- temperaturecooled
- customto give a white solid
- customThis was isolated as 1.2g
出典と根拠
- ORDレコード
- ord-4207c6ba287347beaf6154113f8adf6a
- 出典データセット
- uspto-grants-1976_06
- 特許番号
- US03966947
反応ノート
読み込み中…