Methylamine → 9,10-Anthracenedione, 1,5-bis(methylamino)-

HRID 1659598

反応式

HRID 1659598 の反応式
[N+:1]([C:4]1C2C(=O)C3C(=C([N+]([O-])=O)C=CC=3)C(=O)C=2C=CC=1)([O-])=O.[N+]([C:26]1[C:39]2[C:38](=[O:40])[C:37]3[C:32](=[CH:33][CH:34]=[CH:35][C:36]=3[N+:41]([O-])=O)[C:31](=[O:44])[C:30]=2[CH:29]=[CH:28][CH:27]=1)([O-])=O.[N+]([C:48]1C2C(=O)C3C(=CC=CC=3)C(=O)C=2C=CC=1)([O-])=O.[N+:64]([C:67]1[C:80]2[C:79](=[O:81])[C:78]3[C:73](=[CH:74][C:75]([N+]([O-])=O)=[CH:76][CH:77]=3)[C:72](=[O:85])[C:71]=2[CH:70]=[CH:69][CH:68]=1)([O-])=O.[N+]([C:89]1C2C(=O)C3C(=CC=C([N+]([O-])=O)C=3)C(=O)C=2C=CC=1)([O-])=O.[CH3:108][NH2:109]>>[CH3:4][NH:1][C:29]1[C:30]2[C:31](=[O:44])[C:32]3[C:37](=[C:36]([NH:41][CH3:48])[CH:35]=[CH:34][CH:33]=3)[C:38](=[O:40])[C:39]=2[CH:26]=[CH:27][CH:28]=1.[CH3:108][NH:109][C:77]1[C:78]2[C:79](=[O:81])[C:80]3[C:71](=[CH:70][CH:69]=[CH:68][C:67]=3[NH:64][CH3:89])[C:72](=[O:85])[C:73]=2[CH:74]=[CH:75][CH:76]=1

参加物

8

反応物 6

HCID 6329MethylamineHCID 67041-NitroanthraquinoneHCID 67059,10-Anthracenedione, 1,5-dinitro-2 回HCID 672101,8-Dinitro-9,10-anthraquinone2 回HCID 741461,6-DinitroanthraquinoneHCID 741471,7-Dinitroanthraquinone

生成物 2

HCID 763389,10-Anthracenedione, 1,5-bis(methylamino)-HCID 1089219,10-Anthracenedione, 1,8-bis(methylamino)-

実験手順

subjecting 1,5-dinitro-anthraquinone or 1,8-dinitroanthraquinone or their mixtures thereof or mixtures of nitration residues of 1-nitro-anthraquinone, 1,5-dinitro-anthraquinone, 1,6-dinitro-anthraquinone, 1,7-dinitro-anthraquinone and 1,8-dinitro-anthraquinone to aminolysis with methylamine to give 1,5-dimethylaminoanthraquinone or 1,8-dimethylaminoanthraquinone or their mixtures or corresponding mixtures of dimethylamino residues;

出典と根拠

ORDレコード
ord-7632011165304981afaeac464803f238
出典データセット
uspto-grants-1981_12
特許番号
US04304725

関連ノート

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