Toluene → 4-Hydroxyphenylthio cyclododecadiene

反応式

[SH:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[CH:4][CH:3]=1.[CH:9]1[CH2:20][CH2:19]C=CCCC=C[CH2:12][CH2:11][CH:10]=1.[C:21]1(C)[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1>>[OH:8][C:5]1[CH2:4][CH2:3][CH2:12][CH2:11][CH2:10][CH2:9][CH2:20][CH2:19][C:2]([S:1][C:21]2[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=2)=[CH:7][CH:6]=1

参加物

反応物 3

HCID 1140Toluene

HCID 126681,5,9-Cyclododecatriene

HCID 2401474-Mercaptophenol

生成物 1

HCID 704100744-Hydroxyphenylthio cyclododecadiene

反応条件

温度: 40 °C

実験手順

To the reactor of Example 1 was added 100.8 grams of 4-mercaptophenol and 100 ml toluene. While maintaining the reaction mixture at 40° C. 32.6 grams of 1,5,9-cyclododecatriene was added over a 20 minute period. The mixture was agitated for 24 hours and then stripped to a pot temperature of 220° C. and 11 mm. Hg. to yield 46 grams of product.